X and Start are bound to the same function, which is to interact with a nearby object or bringing up the map/stats/save screen when you're not near anything. I opted to bind both keys to the same function so it's a bit more convenient, since people are used to X being a key to interact with, and start as a menu button.
I bought this game long ago and it was in my backlog, I just beat it with this profile and Xpadder. Have fun, all.
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;--- Xpadder Profile Data --- DataType=Profile Version=2013.07.18 Name=VVVVVV Set1Button1Name=Action Set1Button1Slots=Space Set1Button3Name=Map / Interact Set1Button3Slots=Enter Set1Button7Name=Quit Game Set1Button7Slots=Escape Set1Button8Name=Map / Interact Set1Button8Slots=Enter Set1DPadRightName=Move Right Set1DPadRightSlots=Arrow Right Set1DPadLeftName=Move Left Set1DPadLeftSlots=Arrow Left Set1Stick1RightName=Move Right Set1Stick1RightSlots=Arrow Right Set1Stick1LeftName=Move Left Set1Stick1LeftSlots=Arrow Left